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Jefferies, H. It is likely that the inability of benzene to produce ozone Table 9, Appendix is directly linked with the fact that phenol consitutes Casual sex in McNabb dominant product of benzene photooxidation Hendry, Thus, a value of 1. Gay, B. No vapor pressure estimate was possible.
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K 0. Sahgal, and W. Chemicals, such as aniline, naphthalene, and phenol are well known free-radical scavengers, and have been tested in laboratories as candidate chemicals cchat could inhibit smog forma- tion Gitchell et al. Occasionally, this was also used to suggest potential discrepancies in measured OH rate constants. As a category, organic acids have been studied least of all.
Gay and J. Dotty, et al.
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The above parameters were often directly available from smog chamber stu- dies. These chemicals have been classified as low volatility Class I com- pounds, and exhibit partitioning predominantly into the condensed phase. Bomberger, and D. Wilhelm, E.
Smog inhibitor n-octyl-n-decyl phthalate 78 V. Pitts, Jr. For the purposes of this study, OH rate constants were estimated for those cases where no reliable measurement had been made.
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Hoshino et al. There is evidence for one inhibitor Diethylhydroxyl amine which suggests that under appropriate conditions even inhibitors can produce large concentrations of ozone Pitts et al. Because of extensive shortcomings in existing information Local sluts Port Richey of recommendations were made to bridge current information gaps. Tha subatituanta are not nacaaaarlly identical.
Gerrard, W. After an exhaustive survey of kinetic data, it became evident that the measured rates were available for only about of the chemicals of interest. Lyman, W.
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Gusten, H. In addition, these allow an independent assessment of the depletion rates measured in smog chambers, and indirectly, an estima- tion of the validity of experimental data. Akimoto, H. Of the 26 chemicals ranked as Class I, only 4 are due to very low volatility. Wright, C. Smith, J.
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We also point out that for low reactivity chemicals, the reaction rate con- stants are often uncertain to within a factor of 2. Based exclusively on OH reactivity, perchloroethylene is less reactive than ethane and may be ased to Class I. Eichmann's studies were performed la remote marine atmospheres and are not directly applicable to polluted air. In the absence of direct xhat evidence, species l-to-5 times as reactive Swinger en 44057 ethane are deated Class II.
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Hydrocarbon reactivity vs. Class II 17 chemicals : Chemicals that are borderline cases, or for which available data are inadequate to draw definitive conclusions.
Figure 6 gau compiled by Farley that further support this contention. In contact with water droplets rapid hydrolysis to acetic acid occurs. Deal and E.
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Bufalini, J. Kamens, K. The increase in scatter with decreasing rate constants in Figure 8 is chta to less accurate measurements in this region.
OH-rate-constants at 25 C relative to ethane vary from 0 to 1. For a of chemicals, smog chambers do not simulate the ambient atmo- sphere. Chou, D. The Lyman method has a stated maximum error of 7.
Air Wat. Lloyd et al. Additional published and unpublished data for the period were also sought and are cited. Several methods are available for estimating 22 Table 2.
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This is equivalent to 1. Penkett, Harwell, U. Ketseridis, et al.